You can print 3x5 cards from MS Word or another application that will allow that card size. Simply select it in the page setup properties and load the cards, face down in the photo tray, ensuring they are pushed to the back of the tray. Insert them with the 3" side into the tray first, not the 5" side. Once the printer knows you are printing 3x5 cards and senses them in the photo tray it will work. Good luck!
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